Abstract of Infrared Plastic Solar Cell
Nanotechnology is the nexus of sciences.
Nanotechnology is the engineering of tiny machines - the projected
ability to build things from the bottom up using techniques and tools
being developed today to make complete, highly advanced products. It
includes anything smaller than 100 nanometers with novel properties. As
the pool of available resources is being exhausted, the demand for
resources that are everlasting and eco-friendly is increasing day by
day. One such form is the solar energy. The advent of solar energy just
about solved all the problems. As such solar energy is very useful. But
the conventional solar cells that are used to harness solar energy are
less efficient and cannot function properly on a cloudy day. The use of
nanotechnology in the solar cells created an opportunity to overcome
this problem, thereby increasing the efficiency. This paper deals with
an offshoot in the advancement of nanotechnology, its implementation in
solar cells and its advantage over the conventional commercial solar
cell.
In order to the miniaturization of integrated
circuits well into the present century, it is likely that present day,
nano-scale or nano electronic device designs will be replaced with new
designs for devices that take advantage of the quantum mechanical
effects that dominate on the much smaller ,nanometer scale .
Nanotechnology is often referred to as general purpose technology. That
is because in its mature form it will have significant impact on almost
all industries and all areas of society. It offers better built, longer
lasting, cleaner, safer and smarter products for the home, for
ammunition, for medicine and for industries for ages. These properties
of nanotechnology have been made use of in solar cells. Solar energy is
really an abundant source that is renewable and pollution free. This
form of energy has very wide applications ranging from small household
items, calculators to larger things like two wheelers, cars etc. they
make use of solar cell that coverts the energy from the sun into
required form.
Working Of Conventional Solar Cell
Basically conventional type solar cells Photovoltaic (PV) cells
are made of special materials called semiconductors such as silicon,
which is currently the most commonly used. Basically, when light strikes
the cell, a certain portion of it is absorbed within the semiconductor
material. This means that the energy of the absorbed light is
transferred to the semiconductor. The energy knocks electrons loose,
allowing them to flow freely. PV cells also all have one or more
electric fields that act to force electrons freed by light absorption to
flow in a certain direction. This flow of electrons is a current, and
by placing metal contacts on the top and bottom of the PV cell, we can
draw that current off to use externally.
For example, the current can power a calculator. This current, together with the cell's voltage (which is a result of its built-in electric field or fields), defines the power (or wattage) that the solar cell can produce. Conventional semiconductor solar cells are made by polycrystalline silicon or in the case of highest efficiency ones crystalline gallium arsenide. But by this type of solar cell, it is observed that, only 35% of the suns total energy falling on it could be judiciously used. Also, this is not so favorable on cloudy days, thus creating a problem. This major drawback led to the thought of development of a new type of solar cell embedded with nanotechnology. The process involved in this is almost the same as explained earlier. But the basic difference lies in the absorption of the wavelength of light from the sun.
Scientists have invented a plastic solar cell that can turn the
suns power into electric energy even on a cloudy day. Plastic solar
cells are not new .But existing materials are only able to harness the
sun’s visible light. While half of the sun’s power lies in the visible
spectrum, the other half lies in the infrared spectrum. The new material
is first plastic compound that is able to harness infrared portion.
Every warm body emits heat. This heat is emitted even by man and by
animals, even when it is dark outside. The plastic material uses
nanotechnology and contains the 1stgeneration solar cells that can
harness the sun’s invisible infrared rays. This breakthrough made us to
believe that plastic solar cells could one day become more efficient
than the current solar cell.
The researchers combined specially designed nano particles called
quantum dots with a polymer to make the plastic that can detect energy
in the infrared. With further advances the new PLASTIC SOLAR CELL could
allow up to 30% of sun’s radiant energy to be harnessed completely when
compared to only 6% in today plastic best plastic solar cells. A large
amount of sun’s energy could be harnessed through solar farms and used
to power all our energy needs. This could potentially displace other
source of electrical production that produce green house gases like
coal. Solar energy reaching the earth is 10000 times than what we
consume.
If we could cover 0.1% of the earth’s surface with the solar farms we could replace all our energy habits with a source of power which is clear and renewable. The first crude solar cells have achieved efficiencies of today’s standard commercial photovoltaic’s the best solar cell, which are very expensive semiconductor laminates convert at most, 35% of the sun’s energy into electricity.
The technology takes advantage of recent advances in nanotechnology specifically the production of nanocrystals and nanorods. These are chemically pure clusters of 100 to 100000 atoms with dimensions of the order of a nanometer, or a billionth of a meter. Because of their small size, they exhibit unusual and interesting properties governed by quantum mechanics, such as the absorption of different colors of light depending upon their size. Nanorods were made of a reliable size out of cadmium selenide, a semi conducting material.
Nanorods are manufactured in a beaker containing cadmium selenide, aiming for rods of diameter-7 nanometers to absorb as much sunlight as possible. The length of the nanorods may be approximately 60nanometers.Then the nanorods are mixed with a plastic semiconductor called p3ht-poly-(3-hexylthiophene) a transparent electrode is coated with the mixture. The thickness, 200 nanometers-a thousandth the thickness of a human hair-is a factor of 10 less than the micron-thickness of semiconductor solar cells. An aluminium coating acting as the back electrode completed the device. The nanorods act like wires. When they absorb light of a specific wavelength, they generate an electron plus an electron hole-a vacancy in the crystal that moves around just like an electron. The electron travels the length of the rod until it is collected by aluminium electrode. The hole is transferred to the plastic, which is known as a hole-carrier, and conveyed to the electrode, creating a current.
They also hope to tune the nanorods to absorb different colors to span the spectrum of sunlight. An eventual solar cell has three layers each made of nanorods that absorb at different wavelength
Though at present, cost is a major drawback, it is bound be solved in the near future as scientists are working in that direction.
As explained earlier, if the solar farms can become a reality, it could possibly solve the planets problem of depending too much on the fossil fuels, without a chance of even polluting the environment.
For example, the current can power a calculator. This current, together with the cell's voltage (which is a result of its built-in electric field or fields), defines the power (or wattage) that the solar cell can produce. Conventional semiconductor solar cells are made by polycrystalline silicon or in the case of highest efficiency ones crystalline gallium arsenide. But by this type of solar cell, it is observed that, only 35% of the suns total energy falling on it could be judiciously used. Also, this is not so favorable on cloudy days, thus creating a problem. This major drawback led to the thought of development of a new type of solar cell embedded with nanotechnology. The process involved in this is almost the same as explained earlier. But the basic difference lies in the absorption of the wavelength of light from the sun.
Infrared Plastic Solar Cell
If we could cover 0.1% of the earth’s surface with the solar farms we could replace all our energy habits with a source of power which is clear and renewable. The first crude solar cells have achieved efficiencies of today’s standard commercial photovoltaic’s the best solar cell, which are very expensive semiconductor laminates convert at most, 35% of the sun’s energy into electricity.
Working of Plastic Solar Cell
The solar cell created is actually a hybrid, comprised of tiny
nanorods dispersed in an organic polymer or plastic. A layer only 200
nanometers thick is sandwiched between electrodes and can produce at
present about .7 volts. The electrode layers and nanorods /polymer
layers could be applied in separate coats, making production fairly
easy. And unlike today's semiconductor-based photovoltaic devices,
plastic solar cells can be manufactured in solution in a beaker without
the need for clean rooms or vacuum chambers.The technology takes advantage of recent advances in nanotechnology specifically the production of nanocrystals and nanorods. These are chemically pure clusters of 100 to 100000 atoms with dimensions of the order of a nanometer, or a billionth of a meter. Because of their small size, they exhibit unusual and interesting properties governed by quantum mechanics, such as the absorption of different colors of light depending upon their size. Nanorods were made of a reliable size out of cadmium selenide, a semi conducting material.
Nanorods are manufactured in a beaker containing cadmium selenide, aiming for rods of diameter-7 nanometers to absorb as much sunlight as possible. The length of the nanorods may be approximately 60nanometers.Then the nanorods are mixed with a plastic semiconductor called p3ht-poly-(3-hexylthiophene) a transparent electrode is coated with the mixture. The thickness, 200 nanometers-a thousandth the thickness of a human hair-is a factor of 10 less than the micron-thickness of semiconductor solar cells. An aluminium coating acting as the back electrode completed the device. The nanorods act like wires. When they absorb light of a specific wavelength, they generate an electron plus an electron hole-a vacancy in the crystal that moves around just like an electron. The electron travels the length of the rod until it is collected by aluminium electrode. The hole is transferred to the plastic, which is known as a hole-carrier, and conveyed to the electrode, creating a current.
Improvements
Some of the obvious improvements include better light collection
and concentration, which already are employed in commercial solar cells.
Significant improvements can be made in the plastic, nanorods mix, too,
ideally packing the nanorods closer together, perpendicular to the
electrodes, using minimal polymer, or even none-the nanorods would
transfer their electrons more directly to the electrode. In their
first-generation solar cells, the nanorods are jumbled up in the
polymer, leading to losses of current via electron-hole recombination
and thus lower efficiency. They also hope to tune the nanorods to absorb different colors to span the spectrum of sunlight. An eventual solar cell has three layers each made of nanorods that absorb at different wavelength
Conclusion and Future Scope
Plastic solar cells help in exploiting the infrared radiation from
the sun's rays. They are more effective when compared to the
conventional solar cell. The major advantage they enjoy is that they can
even work on cloudy days, which is not possible in the former. They are
more compact and less bulky. Though at present, cost is a major drawback, it is bound be solved in the near future as scientists are working in that direction.
As explained earlier, if the solar farms can become a reality, it could possibly solve the planets problem of depending too much on the fossil fuels, without a chance of even polluting the environment.
References
1. Nanomaterials: Synthesis, Properties and Applications :
Edelstein, A. S., Cammarata, R. C., Eds.; Institute of Physics
Publishing: Bristol and Philadelphia, 1996. 2. The Coming Era of Nanotechnology ; 1987. Drexler, K. Eric, Doubleday; New York
3. A gentle introduction to the next big idea-Mark A. Ratner, Daniel Ratner.
4. Introduction to nanotechnology- Charles P Poole, Frank J Owens
5. The clean power revolution- Troy Helming
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